The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
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Additive Manufacturing & 3D Printing
Can 3D Printed Mold Tools Solve Your Supply Chain Challenges?
The age-old supply chain challenge - do order production tooling without completing design validation in end-use material in order to save weeks to months of lead times? With quick-turn injection molded parts from 3D printed tools, you don’t have to sacrifice the prototype phase to meet product deadlines. At a fraction of the cost and time of traditional steel and aluminum tools, designers can leverage this technology to iterate new designs many times over - and FAST. Materials ranging from commodity to high-performance resins can run on these tools with complex geometries. This webinar will highlight the benefits of this technology, use cases, and customer case studies where this solution helped bridge the gap between design and production tooling.
Changes In Polyamide 11 Microstructure And Chemistry During Selective Laser Sintering
A polyamide 11/carbon black (PA11/CB) SLS nanocomposite printing powder was characterized throughout a laser area energy density range (express by using Andrew’s numbers, AN) to elucidate significant changes to the PA11 microstructure and chemistry during the SLS printing process. We will show that there are specific microstructural changes that occur in PA11, some gradual and others more striking, between the as received PA11/CB powder and printed parts. The melting temperature (Tm), percent crystallinity (Xc), lamellae thickness (lc) and dhkl spacing of PA11 were all shown to change significantly upon printing, whereas the molecular weight was shown to have a rather gradual increase as a function of AN. These results imply that the printing conditions used result in an irreversible change in PA11 polymer microstructure and chemistry, and correlate well to the measured mechanical behavior of parts print with corresponding AN. The use of DSC, XRD, and molecular weight analysis provides a more complete picture of the changes due to the SLS printing process and can help optimize the printing parameters to create high-quality printed parts.
Curing Behavior Simulator For Robotic 3D Printing Of Uvcurable Thermoset Polymers
Robotic 3D printing systems utilizing photopolymers can enable free-standing structures, large-scale printing, extensive mobility, and increased part complexity. However, to better estimate robotic printing parameters and eliminate expensive trial-and-error approaches, a simulation framework for curing behavior is needed. In this work, an autocatalytic curing model, considering printing speed, UV light intensity, spotlight diameter, and filament thickness, was used to create a MATLAB simulation to study the effect of different printing parameters. The printed filament was discretized into a set number of elements over its length and thickness. UV light exposure time above each element was derived based on spot diameter and printing speed. This simulation framework, combined with experimental data (real-time ATR-FTIR), can better inform decisions regarding printing parameters selection. Overall, it was estimated that a speed ≤ 3 mm/s with a filament thickness ≤ 2 mm would produce acceptable ranges of degrees of cure at different UV light intensities and spot diameters. Finally, control of printing parameters (robotic arm movement and UV light intensity) to obtain a specific degree of cure (DoC) ensuring structural rigidity is demonstrated for a two-degree-of-freedom manipulator, showing both the desired endeffector position and the desired DoC are achieved in four seconds.
Potential Of Five-Axis Kinematic Systems For Additive Manufacturing Using Fused Deposition Modelling (FDM)
Fused Deposition Modelling (FDM) technology is a widely used additive manufacturing processes. In this process, a plastic filament is fed to a nozzle, melted there and deposited in the X, Y direction based on an imported geometry. Afterwards the print bed moves one layer in the Z direction and starts depositing the plastic again in the X, Y-direction. These steps are repeated until the component is completely built up. In a recently developed system by one of the authors, the degrees of freedom in movement of the print head are extended to five axes: X, Y, Z-movement in translational direction plus an additional degree of rotation of the print bed and the possibility to tilt the print head with respect to the printed surface. Thereby, the surface quality and the geometric accuracy for rotationally symmetrical parts are intended to be improved. This paper investigates the potential of the additional motion axes with respect to part quality. To determine the accuracy, surface quality and the ability to print overhangs, tests have been carried out and compared to conventional manufactured FDM parts (X, Y, Z-kinematics). In a further step, the printing of the parts after model preparation in polar coordinates is compared to printing in Cartesian coordinates. To investigate the influence of the print head adjustment on part quality, namely surface roughness, test runs were performed with print head adjusted at different angles to the surface. Suitable demonstrators were developed for this purpose and evaluated in comparison with manufactured FDM parts using commercially available printers limited to X, Y, Z-movement only. The tests show that the recently developed 5-axis printer has a lot of potential. It’s comparable in performance to a commercially available FDM printer from the mid-price segment. The possibility of tilting the print head is the biggest advantage of the system. This has significantly improved part quality when printing overhangs and angled surfaces. The comparison between polar and Cartesian coordinates showed an improvement in surface quality for cylindrical parts printed by polar coordinates.
Fabrication Of Expandable Filaments Towards In-Situ Foam 3D Printing Of Microcellular Poly(Lactic Acid)
The purpose of this study was to investigate the feasibility of in-situ foaming in fused filament fabrication (FFF) process. Development of unexpanded filaments loaded with thermally expandable microspheres, TEM is reported as a feedstock for in-situ foam printing. Four different material compositions, i.e., two grades of polylactic acid, PLA, and two plasticizers (polyethylene glycol, PEG, and triethyl citrate, TEC) were examined. PLA, TEM and plasticizer were dry blended and fed into the extruder. The filaments were then extruded at the lowest possible barrel temperatures, collected by a filament winder, and used for FFF printing process. The results showed that PLA Ingeo 4043D (MFR=6 g/10min) provides a more favorable temperature window for the suppression of TEM expansion during extrusion process, compared to PLA Ingeo 3052D (MFR=14 g/10min). TEC plasticizer was also found to effectively lower the process temperatures without adversely interacting with the TEM particles. Consequently, unexpanded filaments of PLA4043D/TEM5%/TEC2% was successfully fabricated with a density value of 1.16 g/cm3, which is only ~4.5% lower than the theoretical density value. The in-situ foaming in FFF process was then successfully demonstrated. The printed foams revealed a uniform cellular structure, reproducible dimensions, as well as less print marks on the surface, compared to the solid counterparts.
Improving Part Properties During Injection Molding With 3D Printed Co2 Cooled Plastic Mold Inserts
This paper describes the development of innovative temperature control concepts for use in additively manufactured inserts based on CO2. These have been successfully investigated for their suitability in small batch production. The additive manufacturing processes have been evaluated in terms of their suitability for the production of mold inserts. It has been possible to reduce the time required to prepare the inserts. In the investigation of suitable plastics, POM has proven to be suitable. Of the generative manufacturing processes investigated, stereolithography was found to be suitable. Robust manufacturing in the injection molding process with the other additive manufacturing processes was not possible. The manufactured components were examined with regard to their properties and compared with conventionally injection-molded components. It was found that a clear dependence on the manufacturing process of the insert used for production can be observed, especially in the crystalline microstructure of the manufactured components. This makes it difficult to use additively manufactured tool inserts in small-batch production, since the resulting properties of the components in terms of crystallinity and thus distortion are not comparable with injection-molded components. In further investigations, the minimum necessary thermal properties of the printing materials must be determined in order to ensure robust small series production with component crystallinity comparable to the injection molding process.
Turnkey Solution For 3D Metal Printed Conformally Cooled Injection Mold Inserts
In Spring of 2020, Instaversal was contracted to test our newly developed conformal cooling technology, CoolTool™, against existing production benchmarks for a plastic injection molded Pipe Bracket Adapter. The Product Innovator was going through a period of elevated demand where the current cycle time of the existing injection mold tool prohibited them from meeting their demand. When cooling cycles were sped up this led to higher scrap rates due to sink marks. This left the Product Innovator with two options: delay delivery of the product to their top customer with the risk of losing the sale and potentially losing the customer or to invest in additional injection mold tools to double production capacity. To meet the customer’s demand, 100,000 parts needed to be produced in a 60-day time period. This request created conflict with the contract manufacturer. They were being asked to absorb the cost of additional molds to meet the timing or run full 24-hour (Monday-Friday) shifts over the 60-day period which would create losses in revenue by eliminating other clients’ scheduled jobs.
Investigating The Processing Of Stimuli-Responsive Cellulose Nanocrystal Polymer Composites In Graded 3D Printing
Functionally gradient 3d printing is of great importance for polymer composites to be applied in soft robotics or smart electronic devices. Imparting mechanical gradients within the design of new materials would help to prevent premature failure of devices and could reduce strain mismatches. In this work, we first focus on investigating the mechanical gradients and water responsive behavior of cellulose nanocrystal (CNC) / thermoplastic polyurethane (TPU) films by changing the concentration of CNCs. After generating masterbatched feedstocks, CNC/TPU films were extruded with a single screw extruder to obtain 3D printable filaments. The thermal and rheological behavior of the nanocomposite system is characterized to evaluate the mechanical property gradient of CNC/TPU filaments as a function of CNC concentration within a 3D printed geometry.
Increase 3D Print Speeds Up to 2X and Throughput up to 3X with 3D Systems
Recognized over the years for its exceptional prototyping quality and part accuracy, SLA-based additive manufacturing is changing in a big way, with an automation-ready solution that offers up to twice the print speed and up to three times the throughput of existing SLA systems. Join us as we reveal the revolutionary innovations that we are introducing with our new SLA 750 full workflow solution. Providing breakthrough gains in speed, throughput, material performance, and cost-efficiency for factory-floor production, this complete solution features production-grade materials, automation compatibility, and AI-based seamless integration with all factory floor equipment. These innovations now more effectively answer your requirements, from prototyping to production, whether you are a service bureau, automotive, aerospace, consumer goods, foundry or medical device manufacturer.
Large-scale extrusion-based 3D printing for highway culvert rehabilitation
A significant problem associated with repairing deteriorating highway culverts is the resultant lowered flow capacity. This can be mitigated by the use of culvert diffusers. Current culvert diffusers are made using fiberglass reinforced thermosetting epoxy polymers, which require custom made molds. This research work explores the use of large-scale 3D printed thermoplastic polymer composite to manufacture culvert diffusers. The research work shows that 3D printing technology reduces the manufacturing time as well as the cost of culvert diffusers. Large-scale 3D printing technology is well-suited for the manufacture of individualized culvert diffusers with unique geometrical designs without the need for molds. 3D printing technology is also capable of using different materials according to environmental requirements. The use of segmental manufacturing in conjunction with large-scale 3D printing enables the manufacturing of culvert diffusers larger than the build envelope of the 3D printer. Different post-processing techniques used for cutting, finishing, and joining the 3D printed segments are discussed.
Investigation and Realization of Watertight FDM Structures Made of Ultem 9085 in Pressurized Systems
Fused Deposition Modeling (FDM) parts generally show a fluid permeability due to their specific and characteristic strand structure. Therefore, an application including contact with water is difficult and limits the areas of application of this Additive Manufacturing (AM) technology. In this paper the aim is to determine the water tightness of FDM manufactured Ultem 9085 structures in a pressurized system using a suitable test setup. Based on the results, optimization approaches such as parameter modification, variation of the specific part thickness and a surface treatment shall identify if a complete tightness can be realized. For the validation of the results, analysis methods such as CT-scans and macroscopic images are used to determine the component surface.
Effect of Carbon Fiber On the Fracture Toughness of Fused Filament Fabricated CF/ABS Composites
This study reports the effect of carbon fiber (CF) on the fracture toughness of 3D printed carbon fiber/ acrylonitrile butadiene styrene (CF/ABS) composites. Chopped carbon fiber was compounded with ABS to prepare CF/ABS filaments containing 0-25 wt.% CF. Compact tension specimens were designed, 3D printed, and tested to measure the composites’ mode-I fracture toughness, KIc. The results showed CF/ABS composites can be made with up to 25 wt.% loading without any drop in their fracture toughness. In fact, ABS’s KIc increased by ~22% with an introduction of 10 wt.% CF. There was a slight drop in KIc, once the CF content was increased to 15 wt.%. Further increase in CF content from 15 to 25 wt.% did not cause any significant change in KIc and it was found to remain similar to that of the neat ABS. The fracture toughness trend with CF content was qualitatively explained in terms of two competing mechanisms, namely increased actual fracture surface area and less perfect interlayer adhesion at the presence of CFs.
Enabling Mechanically Adaptive 4D-Printing with Cellulose Nanocrystals
Additive manufacturing of stimuli-responsive materials is an area of 4D-printing that is continuing to gain interest. Cellulose nanocrystal (CNC) thermoplastic nanocomposites have been demonstrated as a water responsive, mechanically adaptive material that has promise to generate 4D-printed structures. In this study, a 10wt% CNC thermoplastic polyurethane (TPU) nanocomposite is produced through a masterbatching process and printed using fused filament fabrication (FFF). A design of experiments (DOE) was implemented to establish a processing window to highlight the effects of thermal energy input on printed part mechanical adaptivity (dry vs. wet storage modulus). The combination of high temperatures and low speeds result in thermal energies that induce significant degradation of the CNC/TPU network and reduced absolute values of storage moduli, but the mechanical adaptation persisted for all the printed samples.
Characterization of polypropylene/hydrocarbon resin blends for 3D printing
Additive manufacturing (AM) of polyolefins, such as polypropylene (PP), employing filament-based material extrusion (MatEx) has gained significant research interest in recent years. The semicrystalline nature of PP makes it challenging to process using MatEx. The addition of amorphous low molecular weight hydrocarbon resins into PP matrix was found to delay the onset of crystallization of the blends. The slow crystallization behavior, as evident by the increased crystallization half-times, aided the relaxation of residual stresses during MatEx of PP blends that resulted in manufactured parts with reduced warpage. Rheological characterizations were performed on the PP blends revealing the shear-thinning nature. The combined interaction among crystallization rates, timescales, and morphology was found to affect the interlayer welding process during MatEx. Mild thermal annealing of the manufactured parts resulted in mechanical properties which approach that of injection molded parts.
Machine Learning and Data-Driven Additive Manufacturing
Additive manufacturing has emerged as a disruptive digital manufacturing technology. However, its wild adoption in the industry is still impacted by high entry challenges of design for additive manufacturing, limited materials library, processing defects, and inconsistent product quality. Machine learning has recently gained increasing attention in additive manufacturing due to its exceptional data analysis performance, such as classification, regression, and clustering. This paper provides a review of the state-of-the-art machine learning applications in different domains of additive manufacturing.
Effects of Steam Heat and Dry Heat Sterilization Processes on Polylactic Acid with Hydroxyapatite Composite Printed by FFF
3D printing is used for various medical applications, such as the manufacture of guides for surgical operations, custom medical instruments, and low-cost medical applications. In few of these studies that have been performed, the effect of sterilization on these parts has not been considered yet. The fused filament fabrication process (FFF), which is the most widely used today, is used for the making of these guides and instruments. One of the most used materials in the FFF process is polylactic acid (PLA) due to its ease of printing, however, this could be degraded with the sterilization processes by steam heat and dry heat and lose its dimensional accuracy and resistance, something required for medical applications. The purpose of this study is to determine the effects of the steam heat and dry heat sterilization processes on the mixture of PLA and hydroxyapatite (HA) to check whether this mixture can be used in medical applications that are not implantable in the human body. The percentage by weight of hydroxyapatite used is 5%. To study the effect of sterilization processes already mentioned, 3D specimens were printed for flexural, tensile, Shore Hardness and impact mechanical tests. Thermogravimetric analysis (TGA), Differential scanning calorimetry (DSC) and Dynamic mechanical thermal analysis (DMTA) tests were also performed. It is concluded that the blend of PLA and hydroxyapatite increases its resistance to temperature but decreases its mechanical characteristics.
Shear Induced Crystallization Through Altering Polymer Melt Flow Area
A novel additive manufacturing technique has been developed in the Manufacturing Science Laboratory at Lehigh University.The technique utilizes an extrusion based 3D printer, which has the ability to regulate the areaof the polymer flow inside the extrusion head, thus, allowing precise control over shear rate applied to polymer melt. The controlled shear alters the melt rheology, which in turn controls the evolution of crystallinity in the printed parts. The temporal control of shear translates to spatial control of melt rheology. Thus, the localized evolution of molecular orientation and nucleation/crystallization kinetics as well as the mechanical and optical properties can be precisely controlled during the additive manufacturing process. In this research, a semi crystalline poly-lactic acid (PLA)was utilized to validate the developed technique of controlling the shear rate while printing. The confinement will induce shear on the polymer the degree of which can be controlled by the gap between the conical cavity and theconical extruder tip. The analytical modeling results indicate that this strategy can increase the induced shear rate. Preliminary experimental analysis validated an increase incrystallinity percentage up to 16%.
Fiber Orientation Measurements for Large Additive Manufactured Parts Using Optical and SEM Imaging
Acrylonitrile Butadiene Styrene (ABS) is widely used in additive manufactured part production due to its widespread availability and ease of manufacturing, but unfortunately its structural and thermal performance limits its use in industrial applications. The addition of fiber reinforcements, specially chopped carbon fiber to the ABS matrix has the potential to enhance its structural performance while simultaneously reducing dimensional variations during thermal changes. The quantification of the fiber orientation in the processed ABS bead is important to understand its correlation to the mechanical and structural properties of the processed thermoplastic. This study presents the sample preparation and acquisition of images of fiber orientation and void measurements through optical and scanning electron microscopy of an additive manufactured bead with 13% by weight carbon fiber reinforced ABS. The images are then analyzed, and the fiber orientation is measured using the method of ellipses. The method of ellipses poses a problem of ambiguity for the direction of fiber orientation. With the SEM images the ambiguity problem can be solved using an electrical shadowing technique and the orientation of the fibers in the ABS matrix can be determined. The results for the orientation from the two methods are contrasted, and a discussion is provided on the impact the fiber orientation has on the final part performance. The results also indicate the presence of voids caused by the deposition process that is unique to the currently employed additive manufacturing process which will hamper the final part performance.
3D Printing Sustainable Biocomposites From Recycled PLA and Micro-Crystalline Cellulose
The motivation for this work was to increase the economic life of recycled poly(lactic acid) (rPLA) (30 wt%) by utilizing it with virgin PLA (70 wt%) in the presence of a fiber-based reinforcing filler, micro-crystalline cellulose (MCC) and an epoxy-based chain extender. A conventional melt extrusion technique was used to fabricate the strands with and without MCC and chain extender in the PLA/rPLA blend matrix. It was observed that the complex viscosity of rPLA was improved significantly after the addition of the chain extender, which resolved the issue related to excessive polymer flow during processing and hence made it possible for use in fused deposition modeling (FDM)-based 3D printing. The addition of the chain extender improved the impact strength of 3D the printed PLA/rPLA specimens. The voids in the 3D printed material contributed to the reduced weight of the developed sustainable composites. The modulus and tensile strength of the 3D printed sustainable biocomposites were improved significantly, and impact strength increased by ~10% by reinforcing the blended matrix with 5% of MCC.
Developing Photopolymerizable Acrylate Resin Formulation for Impact Modified 3D Printed Thermosets
This contribution focuses on engineering photopolymerizable acrylate resin formulations for a superior fracture energy absorption of 3D printed acrylate thermosets. Herein, we report a polydimethyl siloxane-based block copolymer as an impact modifier, compatible with the UV curing process, which undergoes reaction induced phase-separation during the 3D printing process to form a rubbery phase sufficient for enhanced impact properties. A systematic investigation of the effect of concentration of the impact modifier on the morphology of rubbery domains and fracture toughness was conducted. Results show that at an optimum concentration of 15 wt.% and particle size of 57 nm, an order of magnitude improvement in the fracture energy release rate is realized. Fractographic analysis of the impact modified thermosets using optical microscopy indicates the presence of significant plastic deformation in an otherwise brittle material. Notably, the engineered acrylate thermosets, at an optimum concentration, exhibit similar improvements in the impact properties irrespective to the print layer thickness and independent of the crack orientation with respect to the printed interphase. Detailed investigation of the failure mechanisms for impact modified thermosets show that the block copolymer diffuses to the interphase during the 3D printing process, resulting in preferential localization of the impact modifier near the print interphase resulting in an isotropic enhancement of the fracture toughness.
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