SPE Library
The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
The SPE Library is just one of the great benefits of being an SPE member! Are you taking advantage of all of your SPE Benefits?
Conference Proceedings
Control of Morphology of Polypropylene and Noryl Blend via Melt Mixing
Yanmei Li, Hung-Jue Sue, Brian Coleman, May 2001
Morphological development of polypropylene/Noryl blends as a function of composition and processing conditions is studied. Effects of processing conditions such as screw speed and residence time, on the morphology and mechanical properties of PP/Noryl blends are investigated. The processing-morphology-property relationship in PP blends is discussed.
Application of Fused Deposition Modelling in Spray Metal Tooling for Injection Moulding
S.H. Masood, M. Bahri, I. Harianton, May 2001
This paper presents a modified spray metal tooling procedure based on FDM rapid prototyping process, where parting lines were defined in the design stage to simplify and accelerate the spray metal tooling. Core and cavity inserts for injection moulding of a gas turbine blade were created using the modified procedure and successfully injected using LDPE. The procedure significantly shortens and simplifies the tool fabrication process, particularly for complex shapes, when manual parting lines establishment is too complicated and time consuming.
The Effect of Crystallinity on Oxygen and Carbon Dioxide Gas Barrier Properties of PET
Jun Lin, Sergei Shenogin, Sergei Nazarenko, D.A. Schiraldi, May 2001
Gas barrier of cold crystallized poly(ethylene terephthalate) (PET) was studied as a function of crystallinity. Changes of permeability and solubility versus crystallinity showed complex behavior, which can not be understood in terms of traditional two-phase approach. The data, however, were amenable to interpretation by three-phase model where, in addition to regular amorphous and crystalline phase, the rigid" amorphous phase with density lower than the density of regular amorphous phase was considered."
Viscoelastic Material Characterization at Large Deformation
Karel Kouba, Petr Novotny, Armin Kech, May 2001
New method was developed for measuring stress-strain at large deformation typical for thermoforming. Method is similar to plug assisted forming with both large strain and high strain rate. Numerical method was developed to get use of reverse engineering for fitting of non-linear parameters of suitable viscoelastic model. The aim of the method is providing reliable data for computer simulation of thermoforming.
Predictive Control of Cavity Pressure during Injection Filling
Rickey Dubay, May 2001
Cavity pressure is a good indicator during injection molding for achieving high part quality and maintaining consistent part weight and overall dimensions. Its trajectory during the filling phase of injection is highly dependent on other molding variables. The repeatable control of cavity pressure is therefore vital for producing parts with tight tolerances. A predictive controller for cavity pressure control during cavity filling was developed and implemented. The controller was able to provide cavity pressure ramp rates ranging from 10 to 35 KPa/ms under high injection speeds.
Metallocene Catalyst Mixture for Propylene Polymerization
Mariana Poloponsky, Érica Gervasoni Chaves, Maria de Fátima V. Marques, May 2001
Metallocene mixtures have been used in order to design polymers with broader polydispersity, intending to improve polymer processing. In this work, the properties of isotactic polypropylene obtained by a mixture of (1) SiMe2(Ind)2HfCl2 and (2) SiMe2(Ind)2ZrCl2 , in different proportions, were investigated. The catalyst activities for the mixtures were lower compared to the individual complexes. We observed polymers showing broader molecular weight distribution, with a bimodal Gel Permeation Chromatography curve at 50/50 (1)/(2).
Syndiotactic Polypropylene from Metallocene Mixture
Érica Gervasoni Chaves, Mariana Poloponsky, Maria de Fátima V. Marques, May 2001
Considering the real interest in syndiotactic polypropylene (s-PP) and the possibility to design polymers with desired properties using metallocene catalyst mixtures, this work investigates the characteristics of s-PP produced by a mixture of (1) Et(Flu)(Cp)ZrCl2 and (2) Ph2C(Flu)(Cp)ZrCl2 in different proportions. By the results we observed that the polymers obtained from the mixed systems showed higher molecular weight and broader molecular weight distribution than the isolated polypropylenes.
Thermoset Filling Imbalances in Geometrically Balanced Runner Systems
David A. Hoffman, John P. Beaumont, May 2001
Shear induced variations created within runner systems dramatically affect the filling of the industry standard geometrically balanced runner systems. These variations not only cause imbalances in cavity filling, but may also impact the polymer curing properties and the mechanical properties of the molded product. This paper reveals the severity of the imbalance within thermosetting materials, its potential effect on the molded product, and a new technique used to solve the imbalances.
Spatially Resolved Studies of Polymer Film Dynamics
Boris B. Akhremitchev, Sabah Al-Maawali, Jason E. Bemis, Gilbert C. Walker, May 2001
We have developed several new scanning probe methods for analyzing polymers at surfaces. We present a technique for studying single polymer chains. We describe model for polymer dynamics on an AFM tip, and applications of the technique to analysis of polymer surface polydispersity and irreversible aspects of adhesion. We also describe developments in apertureless near field scanning infrared microscopy (ANSIM), to obtain IR spectra of surfaces at high spatial resolution.
Syndiotactic Polypropylene Using Different Supported Metallocene Catalyst
Queli C. Bastos, Simone C. Moreira, Juliana D. Rego, Maria de Fátima V. Marques, May 2001
Polymerizations of propylene were carried out with ?2C(Flu)(Cp)ZrCl2 catalyst supported on silica, sodic modernite (NaM) and ZSM-5. The molecular weight, molecular weight distribution, melting point and crystallinity of the obtained polymers and also catalytic activity were examined. The results report very high activities for the heterogeneous systems, specially with ZSM-5 as carrier. Higher melting point and crystallinity degree were presented in polypropylene synthesized with the catalyst supported on NaM.
Dimensional Stability of LDPE Foams: Modeling and Experiments
Chi-Tai Yang, Kevin L. Lee, S.-T. Lee, May 2001
The thickness change of extruded LDPE foam to the blowing agent and air counter diffusion during the post-extrusion aging process is modeled. The blowing agent and air counter diffusion equations are coupled with the viscoelastic equations to model the foam volume shrinkage and recovery processes in a closed-cellular low-density LDPE foam. The variables studied include polymer elastic and viscous constants, foam sheet thickness, cell count and foam density. The mathematical model is also compared with experimental data.
Failure Analysis Case Study - A Systems Solution
Michael P. Sepe, May 2001
Failure analysis typically employs a series of appropriate tests that result in a conclusion about the cause or causes of a product failure. Often the problem involves an interaction between the plastic part and other components in the product or between the plastic part and application conditions. Identifying these interactions is an important part of developing a solution that resolves the problem without unduly increasing costs. This paper outlines a case study in which a proper analysis of the failure mode and knowledge of commercial alternatives led to multiple options for a solution.
What Position on the Viscosity Curve Is the Most Repeatable with Respect to End of Fill Cavity PSI
Sean Mertes, Charley Carlson, John Bozzelli, Mike Groleau, May 2001
For many years, educators in the injection molding industry have suggested that higher injection speeds result in more stable processes when using 2-Stage processes. However, little data exists to verify this assertion. In this paper, injection speeds were varied on a 2-Stage process. Cavity pressure was measured at the end of the cavity to evaluate process stability in the face of several process perturbations. Results supported the claim that higher injection rates reduced overall process variation.
Toughening of Polypropylene with Calcium Carbonate Particles
W.C.J. Zuiderduin, C. Westzaan, H. Huetink, R.J. Gaymans, May 2001
In this paper the influence of precipitated calcium carbonate (PCC) particles on the toughening of polypropylene has been studied. It has been shown that the addition of the PCC particles increase the stiffness of the system and at the same time increase the impact resistance. The brittle-to-ductile transition temperature (TBD) was lowered considerably by increasing the calcium carbonate concentration. The debonding of the calcium carbonate particles prior to the yield stress is the dominating step in the toughening mechanism.
Effect of Crystallization Conditions on Spherulitic Texture and Tensile Properties of sPS/PPO Blends
G. Dutt, K.M. Kit, May 2001
Syndiotactic polystyrene (sPS) and poly(phenylene oxide) (PPO) blends, miscible in melt state, were crystallized from melt as well as quenched state at different temperatures. The effect of processing conditions on spherulitic texture, ultimate tensile properties and the mode of fracture was studied. The study suggests that by varying composition and processing conditions in melt miscible blends it is possible to control amorphous domain sizes, which is critical in achieving better mechanical properties
CPI In-Line Compounding Systems
Marvin J. Voelker, Charles D. Weber, May 2001
Composite Products, Inc. has commercialized in-line compounding technology to produce long fiber thermoplastic composites. Turnkey systems continuously compound thermoplastic resin with reinforcements ie. ½ inch chopped glass, carbon or natural fibers to produce finished composites with outstanding toughness. The separation of thermoplastic melt processing and the introduction of glass is key to fiber length retention. The patented technology provides molders the ability to maintain the highest level of physical properties while molding appearance parts. or strongly reduce
Blends of Recycled Polyethylenes and Metallocene Impact Modifiers for Rotational Molding
E. Takács, M. Kontopoulou, J. Vlachopoulos, E. Voldner, K. Nichols, May 2001
This paper describes the development of blends of recycled polyethylenes suitable for rotational molding. The blends consist of recycled post-industrial polyethylene resins and polyolefin plastomer impact modifiers, produced by single-site (metallocene) catalysts. The rheological properties of the blends were found to be favorable for rotational molding. Rotomolded parts provided satisfactory low temperature impact strength and good tensile properties.
Toughening Mechanisms in Fiber-Containing Impact Modified Polymers
Guoxin Sui, Shing-Chung Wong, Chee-Yoon Yue, May 2001
An attempt was made to separate the toughening arising from the presence of fiber and that from the toughened matrix using the essential work of fracture. Toughening mechanisms with fiber inclusions were found to be associated with fiber bridging, debonding and pull-out. It was concluded that such fiber toughening would yield a flat curve when the specific total fracture work was plotted against the ligament length. The technique was able to produce fruitful information regarding design for property synergism in impact modified nylon 6,6.
Prediction of Transient Material Functions of PP Resins Using the Multi-Mode PTT Molecular Network Model
Jaime Bonilla Ríos, Rodolfo Mier Martínez, May 2001
The transient rheological material functions [?(t,?),N1(t,?),?e(t,?) ] of three PP resins are predicted using the multi-mode Phan-Thien and Tanner (PTT) molecular network model. The study also includes the standard quality properties (MFI, XSP, GPC, and DSC) of the resins. The model was coded in C-language, validated with published data (Phan-Thien, 1978) and then used for the prediction of transient material functions. The predictions are in good agreement with the resins' rheological data.
An Experimental Comparison of the Improved Mixing Obtained from a New Barrier Screw Design
Kevin R. Slusarz, Michael R. Thompson, John P. Christiano, May 2001
A comprehensive study looking at both distributive and dispersive mixing for a new screw design was done on a single screw extruder. The findings showed an improvement in mixing performance with this new style barrier screw over a conventional barrier screw design. Mixing performance was evaluated by means of microscopic analysis. To better quantify mixing three different systems will be studied; distribution of a pigment, distribution of an inorganic filler, and dispersion of a minor component in an immiscible blend.
.jpg)
.jpg)
.jpg)
.jpg)
